The following five postulates are stated at the beginning of Euclid's Elements. All of classical geometry is built from these five assumptions.
This last postulate is equivalent to what is known as the parallel postulate:
Given any line and a point not on the line, there exists exactly one line through the point that is parallel to the given line.
As you can see, the 5th postulate is considerably less obvious than the first four. Euclid himself used only the first four postulates ("absolute geometry") for the first 28 propositions of the Elements (perhaps indicating some doubt as to its self-evident nature), but was forced to invoke the parallel postulate on the 29th.